Journal
JOURNAL OF POWER SOURCES
Volume 482, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2020.228899
Keywords
Fibrillated fiber morphology; Paper-based separator; Pore structure; Local microscopic defects; Lithium-ion batteries
Funding
- Natural Science Foundation of Guangdong Province of China [2018A030310399]
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Increasing beating revolutions result in a decrease in the number of coarse fibers and a reduction in the mean fiber diameter of Lyocell fibrillated fiber paper-based separators. The morphology of the fibers has a significant impact on the thickness, pore size, and porosity of the separators, with larger pore size and porosity contributing to better cycle performance at room temperature. However, at lower temperatures, the presence of coarse fibers can lead to local lithium plating and deterioration in cycle performance.
The effect of the morphology of Lyocell fibrillated fibers with different beating revolutions on pore structure and electrochemical properties of Lyocell fibrillated fiber paper-based (LF) separators for lithium-ion batteries is investigated. With raising the beating revolutions from 50,000 to 600,000, the number of coarse fibers decreases from 7851 to 743, and the mean fiber diameter decreases from 374 nm to 171 nm. Both the number of coarse fibers and the mean fiber diameter have good correlation with the thickness, pore size and porosity of the LF separators. The risk of battery short circuit is increased, if the mean pore size of separators is larger than the minimum size of cathode particles. Compared to the PE and PI separators, the LF separators deliver excellent cycle performance with different current densities at 30 degrees C owing to their larger pore size, porosity, and better electrolyte affinity. However, the cycle performance deteriorates at -10 degrees C due to the severe local lithium plating on the graphite surface caused by a large number of coarse fibers with a diameter ranging from 5 mu m to 15 mu m as local microscopic defects.
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