Journal
JOURNAL OF POWER SOURCES
Volume 481, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2020.229120
Keywords
Sodium batteries; Cobalt-based layered oxides; Multi-phase positive electrode; Cathode materials; Phase transition
Funding
- German Research Foundation (DFG) [390874152]
- ERANETMED program EU-MENA
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Layered Na2/3Co2/3Ti1/3O2 oxide prepared via a solid-state process exhibits high charge and discharge capacities in sodium half cells. The P2 structure-type remains stable and dominates electrochemical activity in the investigated potential window. Electrochemical impedance spectroscopy reveals changes in cell impedance during charging and discharging cycles.
Co-based layered Na2/3Co2/3Ti1/3O2 oxide is prepared via a solid-state process and investigated in sodium half cells. X-ray diffraction reveals the presence of several phases in the pristine material with P2 and P3 structure types as the main phases.The mixture of phases shows a smooth charge/discharge curve and the potential steps previously observed for Na2/3Co1-yTiyO2 (y = 0, 0.05, 0.1) have completely vanished. This phase mixture delivers high charge and discharge capacities of 110.5 and104.5 mAh.g(-1), respectively, in the potential range 2-4.2 V as well as a high rate capability. The desodiation/sodiation process of Na2/3Co2/3Ti1/3O2 is investigated by operando diffraction using synchrotron radiation. The P2 structure-type remains stable in the investigated potential window and dominates the electrochemical activity. Electrochemical impedance spectroscopy was conducted during the first charge/discharge cycle and over cycling. The results show that, from OCV till the end of charge, two semi-circles appear in the Nyquist diagram and merge during the following discharge. The total cell impedance increases drastically during Na-insertion at high sodium content (from 50 Omega at 4 V to 375 Omega at 2 V).
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