Phase Transitions in Low-Dimensional Layered Double Perovskites: The Role of the Organic Moieties

Halide double perovskites are an interesting alternative to Pb-containing counterparts as active materials in optoelectronic devices. Low-dimensional double perovskites are fabricated by introducing large organic cations, resulting in organic/inorganic architectures with one or more inorganic octahedra layers separated by organic cations. Here, we synthesized layered double perovskites based on 3D Cs2AgBiBr6, consisting of double (2L) or single (1L) inorganic octahedra layers, using ammonium cations of different sizes and chemical structures. Temperature-dependent Raman spectroscopy revealed phase transition signatures in both inorganic lattice and organic moieties by detecting variations in their vibrational modes. Changes in the conformational arrangement of the organic cations to an ordered state coincided with a phase transition in the 1L systems with the shortest ammonium moieties. Significant changes of photoluminescence intensity observed around the transition temperature suggest that optical properties may be affected by the octahedral tilts emerging at the phase transition.

Automated summary

Halide double perovskites are a promising alternative to Pb-containing materials in optoelectronic devices. By introducing large organic cations, researchers successfully synthesized layered double perovskites, and observed changes in the conformational arrangement of organic cations during phase transitions. Raman spectroscopy and photoluminescence intensity changes provide important insights into the structural variations.