4.6 Article

Phosphotungstic acid immobilized onto ZnO coated zerovalent iron (Fe@ZnO/PW) core/shell magnetic nanocomposite for enhanced photocatalytic bacterial inactivation under visible light

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2020.112907

Keywords

Core/shell; Magnetic nanocomposites; Photocatalyst; Phosphotungstic acid; Bacterial inactivation

Funding

  1. AL-Nahrain Nanorenewable Energy Research Center (NNERC), Al-Nahrain University
  2. Biotechnology Department, College of Science/University of Baghdad

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A magnetic nanocomposite based on phosphotungstic acid was synthesized and used as a recyclable photocatalyst for bacterial inactivation, showing good stability and efficiency in the process.
In this work, phosphotungstic acid (PW)-based magnetic nanocomposite (Fe@ZnO/PW) was synthesized, characterized and used as a recyclable photocatalyst for bacterial inactivation of pathogenic E. Coli bacterium under LED lamps as a light source. Different characterization methods (X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM), vibrating sample magnetometer (VSM), BET surface area and pore volume and UV-vis absorption spectra) were used to characterize the synthesized Fe@ZnO and Fe@ZnO/PW magnetic nanocomposites. The Fe@ZnO/PW nanocomposite retaining magnetic properties was easily separated using an external magnet. Fe@ZnO/PW could completely inactivate 10(7) cfu/ml of E. coli after 2 h of irradiation time. Considerably, Fe@ZnO/PW photocatalyst exhibited good stability and no reduction of its photocatalytic bacterial inactivation performance was observed even after six successive cycles.

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