Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 86, Issue 3, Pages 2100-2106Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c02052
Keywords
-
Categories
Funding
- National Science Foundation [1654029]
- Qatar National Priority Research Program [NPRP11S-1204-170062]
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
- DOE Office of Science [DEAC02-06CH11357]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1654029] Funding Source: National Science Foundation
Ask authors/readers for more resources
An extensive polycyclic pi-system with 23 fused rings was synthesized via a highly efficient borylation reaction, forming four B-N covalent bonds and four B <- N coordinate bonds. The B <- N coordinate bonds not only lock the backbone into a near-coplanar conformation but also decrease the LUMO energy level, demonstrating the dual utility of this strategy for the synthesis of rigid polycyclic molecules and the development of n-type conjugated materials for organic electronics and photovoltaics.
An extensive polycyclic pi-system with 23 fused rings is synthesized via a highly efficient borylation reaction, in which four B-N covalent bonds and four B <- N coordinate bonds are formed in one pot. B <- N coordinate bonds not only lock the backbone into a near-coplanar conformation but also decrease the LUMO energy level to around -3.82 eV, demonstrating the dual utility of this strategy for the synthesis of extensive rigid polycyclic molecules and the development of n-type conjugated materials for organic electronics and organic photovoltaics.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
