Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 86, Issue 1, Pages 1191-1197Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c02091
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Funding
- National Science Foundation [CHE 1566588]
- Washington University in Saint Louis
- National Science Foundation grant (MRI) [CHE 1827756]
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Several additional examples of cascade cyclizations of alpha, beta-unsaturated thioesters are reported, proceeding via two distinct mechanistic pathways: enantioselective acyl transfer promoted by amidine-based catalysts (ABCs) and a racemic chain mechanism mediated by a thiolate nucleophile.
Several additional examples of cascade cyclizations of alpha,beta-unsaturated thioesters proceeding are reported, which proceed via two distinct mechanistic pathways: enantioselective acyl transfer promoted by amidine-based catalysts (ABCs) and a racemic chain mechanism mediated by a thiolate nucleophile.
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