4.6 Article

CuS cluster microspheres anchored on reduced graphene oxide as electrode material for asymmetric supercapacitors with outstanding performance

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Publisher

SPRINGER
DOI: 10.1007/s10854-020-05219-0

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  1. Qing Lan project of Jiangsu Province

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The CuS/rGO composite electrode material demonstrates high specific capacitance and long cycling life, indicating excellent electrochemical performance for potential applications in efficient electrochemical supercapacitors.
Transition metal chalcogenides have been considered as promising electrode materials for high-performance supercapacitors owing to their exceptional electrical conductivity, ultrahigh specific capacity, etc. Herein, CuS/rGO composite electrode material has been rationally prepared by using a facile and efficient strategy, and the synergistic effect of CuS and rGO on the enhanced electrochemical performance is explored. The CuS/rGO electrode with diffusion-controlled feature can deliver a high specific capacitance of 1918.6 F g(- 1) F g (- 1) at 1 A g (- 1) and as well as a long cycling life with 95.4% retention after 5000 cycles at 10 A g (- 1). Charge storage analysis reveals that the dominant diffusion-controlled feature of CuS/rGO electrode is observed. Additionally, the as-synthesized asymmetric supercapacitor by using CuS/rGO electrode exhibited a maximum energy density of 51.1 Wh kg(- 1) at 799.9 W kg(- 1) and a maximum power density of 16007.9 W kg(- 1) (for an energy density of 36.0 Wh kg(- 1)). Besides, it displays excellent cyclic stability with 91.3% capacity retention after 10,000 cycles at 10 A g(- 1). These remarkable electrochemical performances demonstrate that CuS/rGO composite has excellent potential applications in high-efficient electrochemical supercapacitor.

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