Heavy metal ions' poisoning behavior-inspired etched UiO-66/CTS aerogel for Pb(II) and Cd(II) removal from aqueous and apple juice

Here, inspired by the poisoning process of heavy metal in human body that the accidental ingested heavy metal can anchor to the functional groups of DNA/protein/enzyme to exert their toxicities during the rapid blood circulation, we developed the adsorbent that enveloped Etched UiO-66 with abundant functional groups into chitosan (CTS) aerogel to capture Pb(II) and Cd(II) in aqueous and apple juice. SEM, XRD and FTIR spectra were used to characterize the Etched UiO-66/CTS aerogel. The results showed that Etched UiO-66/CTS aerogel has a three-dimensional porous structure, and -OH groups of CTS interact with Zr(IV) of Etched UiO-66 to form the stable UiO-66/CTS aerogel. Benefiting from the intrinsic properties of porous and abundant functional groups, Etched UiO-66/CTS aerogel exhibits satisfactory adsorption capacities of 654.9 mg g(-1) for Pb(II) and 343.9 mg g(-1) for Cd(II) at 45 C. Moreover, the aerogel shows excellent removal efficiencies of 98.21% for Pb(II) and 98.70% for Cd(II) with initial concentration of 1.0 mg L-1 in apple juice with little effect on the quality of apple juice. This strategy of mimetic heavy metal ions' poisoning behavior opens up a new avenue for the removal of heavy metal ions in complex matrices.

Automated summary

A new adsorbent was developed by encapsulating Etched UiO-66 with abundant functional groups into chitosan aerogel, showing high adsorption capacities for Pb(II) and Cd(II) and excellent removal efficiencies in apple juice. This strategy mimicking heavy metal ions' poisoning behavior opens up a new avenue for the removal of heavy metal ions in complex matrices.