4.6 Article

Unique antimicrobial/thermally conductive polymer composites for use in medical electronic devices

Journal

JOURNAL OF APPLIED POLYMER SCIENCE
Volume 138, Issue 13, Pages -

Publisher

WILEY
DOI: 10.1002/app.50113

Keywords

antimicrobial activities; antimicrobial‐ functionalized hexagonal boron nitride nanoplatelets; low melt alloys; thermal conductivity

Funding

  1. National Natural Science Foundation of China [51473097]
  2. Opening Project of State Key Laboratory of Polymer Materials Engineering (Sichuan University) [sklpme2014-3-14]
  3. Sichuan Province Science and Technology Support Program [2019YJ0107]

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A novel ternary composite with excellent antimicrobial and thermal conductive properties was developed to address the common neglect of bacterial growth and accumulation on polymer-based thermal conductive materials used in medical electronic devices. The composite showed 100% antibacterial effectiveness against Escherichia coli and Staphylococcus aureus, with a thermal conductivity enhancement of about 1141% over pure epoxy. This composite not only enhances antimicrobial properties, but also forms a continuous network for heat conduction in the epoxy.
The common neglect of the prominent bacterial growth and accumulation on polymer-based thermal conductive materials used in medical electronic devices will hurt the functionality and lifetime of medical devices, and sometimes even lead to medical accidents. In this study, we developed a novel ternary composite with excellent antimicrobial and thermal conductive properties to solve this problem. This composite was composed of antimicrobial functionalized hexagonal boron nitride (AB@h-BN) nanoplatelets, low melt alloys (LMAs), and epoxy. Antimicrobial testing showed that the AB@h-BN/LMAs/epoxy composites were 100% against both Escherichia coli and Staphylococcus aureus; their antibacterial mechanism was contact killing and was harmless to the environment. Besides enhancing the antimicrobial property, the AB@h-BN nanoplatelets connected the mutually independent LMAs, forming the continuous network for heat conduction in the epoxy. Benefited from this distinctive structure, the thermal conductivity of AB@h-BN/LMAs/epoxy can reach 2.66 Wm(-1) k(-1), which represented an enhancement of about 1141% over the pure epoxy.

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