4.7 Article

Biowaste-sustained MoSe2 composite as an efficient anode for sodium/potassium storage applications

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 850, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.156770

Keywords

Biowaste; MoSe2; CNTs; Sodium ion batteries; Potassium ion batteries; Anode

Funding

  1. National Natural Science Foundation [U1601214]
  2. National Natural Science Foundation of Guangdong Province [U1601214]
  3. Project of the Department of Education of Guangdong Province [2018KTSCX047]
  4. Scientific and Technological Plan of Guangdong Province [2017A040405047]
  5. Special Funds for the Cultivation of Guangdong College Students' Scientific and Technological Innovation [pdjha0126]
  6. Guangdong Basic and Applied Basic Research Foundation [2019A1515011615]

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A high-efficiency anode material for sodium ion batteries and potassium ion batteries was fabricated from biological waste, exhibiting excellent stability and rate performance, as well as a broad working temperature range. These attractive properties mainly originate from the uniform dispersion of MoSe2 particles, tunable pseudocapacitive behavior, and enhanced electron conductivity.
The biological waste of mangosteen epicarp was recycled to fabricate biomass carbon; then, a biowaste-sustained MoSe2/biowaste carbon/carbon nanotubes composite (MoSe2/BC/CNTs) was constructed via a hydrothermal process. As a high-efficiency anode material for sodium ion batteries (SIBS) and potassium ion batteries (PIBs), the MoSe2/BC/CNTs composite displays persistent sodium/potassium ion storage capabilities of 405.0 mA h g(-1) and 415.5 mA h g(-1), respectively, after 250 cycles and excellent rate performances of 336.8 mA h g(-)1 at 5000 mA g(-1) and 247.8 mA h g(-1) at 2000 mA g(-1) in SIBS and PIBs, respectively. Additionally, the MoSe2/BC/CNTs composite has a broad working temperature range from -10 to 60 degrees C and delivers 230.5-585.9 mA h g(-1) in SIBS and 186.7-482.1 mA h g(-1) in PIBs. These attractive electrochemical properties mainly originate from the uniform dispersion of MoSe2 particles, tunable pseudocapacitive behavior and enhanced electron conductivity. The strategy applied to biological waste recycling is expected to have broad application prospects that will contribute to avoiding environmental pollution. (C) 2020 Elsevier B.V. All rights reserved.

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