Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 851, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.156826
Keywords
Co-doped nanofibers; Photocatalysis; Visible-light; Antibiotic; Electrospinning
Categories
Funding
- Basic Science Research Program through the National Research Foundation of Korea [2014R1A5A1009799]
- Ministry of Science, ICT and Future Planning (MSIP), Republic of Korea
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In this study, Fe and Sn co-doped TiO2 nanofibers showed superior photocatalytic efficiency and cycling stability in the degradation of the antibiotic tetracycline under visible light irradiation. The co-doped sample exhibited a dominant anatase phase, enhancing photocatalytic activity, and followed the Langmuir-Hinshelwood kinetic model for photodegradation. Additionally, electron paramagnetic resonance and radical scavenging experiments confirmed the involvement of (OH)-O-center dot and O-center dot(2)- radicals in the degradation process.
The development of multi-functional visible-responsive TiO2-based photocatalysts remains a long-term goal as a promising strategy for dealing with the issue of antibiotic-residues in natural streams. Herein, for the first time, photodecomposition of a typical antibiotic, tetracycline (TC), over Fe and Sn co-doped-TiO2 nanofibers (Fe/Sn-TiO2 NFs) was evaluated under simulated visible-irradiation. A facile PVPassisted electrospinning method was utilized to fabricate a series of TiO2 NF-based photocatalysts. Notably, compared with the pristine and single doped-TiO2 samples, Fe/Sn-TiO2 showed supreme photocatalytic efficiency and cycling photostability, capable of eliminating over 92% of the TC within 60 min after 5 cycles. Benefiting from the shortened band gap to harvest visible-light, the co-doped sample exhibited a dominant anatase phase, which could enhance photocatalytic activity. In addition, a kinetic analysis was performed to verify that the apparent photodegradation rate followed the Langmuir-Hinshelwood kinetic model. Moreover, the favored separation and transmission of chargecarriers in the Fe/Sn-TiO2 were studied using photoluminescence and photoelectrochemical analyses. The Fe/Sn-TiO2 was able to degrade 81.85% and 60.59% of TC in tap and river waters, respectively, after 60 min illumination. Additionally, electron paramagnetic resonance and radical scavenging experiments were carried out to demonstrate that (OH)-O-center dot and O-center dot(2)- radicals were involved in the degradation of TC over Fe/Sn-TiO2. Degradation pathways of TC were investigated using liquid chromatography-mass spectrometry and the enhanced photodegradation mechanism was discussed in detail. Overall, the present work could provide reliable guidelines for the design and synthesis of boosted one-dimensional photocatalysts with potential applications in drug decontamination. (C) 2020 Elsevier B.V. All rights reserved.
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