4.7 Article

Thermodynamic and kinetic studies of the Cu-Zr-Al(-Sn) bulk metallic glass-forming system

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Summary: Fragile-to-strong (FTS) transitions have been observed in all categories of glass-forming systems, leading to a change from Arrhenius to non-Arrhenius viscosity behavior, along with anomalies in various thermodynamic variables. Experimental evidence supports the presence of FTS transitions, where a peak in heat capacity and density extrema with a negative expansion coefficient are found. Spectroscopic analyses also reveal distinct structural changes across these liquid-liquid transitions. Reports of FTS transitions in each category of liquid are reviewed.

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