Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 46, Issue 2, Pages 2617-2629Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2020.10.144
Keywords
Electrolysis; Oxygen evolution reaction; Crystal-layered structure; Overpotential; Tafel slope; Nickel
Categories
Funding
- Centre for Nano and Material Sciences (CNMS), Jain (deemed-to-be) University, Bengaluru [11(39)/17/012/2017SG]
- Ministry of Science and Technology, Department Science and Technology, Government of India [SR/NM/NS-20/2014]
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The paper presents a synthesis method and performance characterization of an efficient and reliable NiFe2O4/rGO hybrid OER electrocatalyst. The optimized catalyst exhibits excellent OER performance in alkaline 1M KOH solution, displaying high activity and stability.
To rescue the future from the global energy crisis and to ensure it with clean and economical hydrogen energy, it is an urgency to develop an efficient OER catalyst, which intensely sluggish the kinetic process of hydrogen production. Herein, we have precisely synthesized an efficient, stable, earth-abundant metal-based NiFe2O4/rGO hybrid OER electrocatalysts by a simple solvothermal method. The measurements including XRD, FTIR, XPS, EDS, SEM, and TEM revealed the prominent structural integrity of catalyst with crystal-layered structure. The rich oxidation chemistry of transition metals and substantially active carbon substrate allows tuning of their electronic properties concerning their concentration, composition, and morphology. The effect of different Ni wt.% (0%, 2%, 4%, and 6%) on the morphology of hybrid as well as on electrochemical performance investigated. The protocols like overpotential required to achieve a current density of 10 mA/cm(2), Tafel slope, ECSA, RF, EIS, stability was utilized to examine the overall abilities of electrocatalyst in alkaline 1 M KOH solution. The optimized NiFe2O4/rGO hybrid with 2 wt % Ni exhibited the excellent OER performance, which delivers a current density of 10 mA/cm(2) at an overpotential of only 302 mV with a small Tafel slope of 63 mV/dec. The high activity of the catalyst is attributed to the synergistic effect of the crystal-layered structure as well as rapid mass-charge transfer. Such, rational design concept of anchoring non-precious metal on carbon in a controlled manner, offering splendid flexibility to tailor electrochemical OER performance. The optimized variations in metal concentration and morphologies, providing a promising route to develop a cost-effective catalyst for advanced energy conversion applications. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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