Journal
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
Volume 102, Issue 19, Pages 8270-8286Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/03067319.2020.1849648
Keywords
Activated carbon; mahogany fruit shell; Pb(II); adsorption; sulphuric acid
Categories
Funding
- UGC-SAP
- DST-FIST
- DST-PURSE [SU/EST/PG/1446]
- DAE-BRNS [36(4)/14/31/2015/36002]
- CSIR, New Delhi, India [31/11/(1092)/2019-EMR-I]
- Human Resources Development Program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) - Korean Government Ministry of Trade, Industry and Energy [20194030202470]
- Priority Research Centers Program through the NRF, Korea - Ministry of Education, Science and Technology [2018R1A6A1A03024334]
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In this study, an adsorbent called mahogany fruit shell activated carbon (MFSAC) was derived from agricultural waste and used for the adsorption of toxic Pb(II) ions. The MFSAC material showed good adsorption capacity and kinetic uptake rate, and could be easily regenerated for repeated use.
An adsorbent, mahogany fruit shell activated carbon(MFSAC), was derived from environmental friendly raw material, i.e. agriculture waste and explored for bench scale adsorption of toxic Pb(II). A facile MFSAC material was synthesised using a chemical activation method using concentrated sulphuric acid as an impregnating (activating) reagent. So derived adsorbent material was characterised by FTIR, XRD, BET, SEM, EDAX, TGA and XPS techniques to know the properties and plausible adsorption mechanism. Bench scale adsorption of toxic Pb(II) and maximum adsorption capacity of MFSAC were exhibited through batch adsorption experiments. The effect of physico-chemical parameters such as pH (1-7), MFSAC amount (0.5-5.0 g L-1), Pb(II) concentration (200-1000 mgL(-1)), contact period (60-600 min) and orbital shaking speed (60-200 rpm) was studied for maximum removal of Pb(II) upto 99.70 +/- 0.17%. The experimental data follow the Langmuir adsorption isotherm with a maximum monolayer adsorption capacity 322.28 mg g(-1)and pseudo-second-order kinetic uptake rate. The thermodynamic and temperature study revealed that the adsorption process was spontaneous and endothermic in nature (Delta H-o = 43.37 kJ mole(-1), Delta S-o = 158.02 J mol(-1)K(-1)). Most importantly, the MFSAC adsorbent was successfully regenerated and reused with conspicuous performance up to five consecutive cycles. The bench-scale adsorption with simple synthesis route, good stability and remarkable regeneration capability makes the MFSAC as an encouraging adsorbent for wastewater treatment.
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