Journal
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
Volume 45, Issue 4, Pages 6273-6284Publisher
WILEY
DOI: 10.1002/er.6250
Keywords
carbon dioxide; dezincification; electrodeposition; electroreduction; Sn-MWCNT/Cu electrode
Categories
Funding
- Guangxi Technology Base and Talent Subject [GUIKE AD18126001]
- International Academic Cooperation and Exchange Program of Shanghai Science and Technology Committee [18160723600]
- Special Fund for Guangxi Distinguished Expert
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A novel method for fabricating nanoporous and structured Sn-based catalyst electrodes has been developed, which can achieve high HCOO- Faradaic efficiency in CO2-saturated solutions by controlling the contents of Zn and MWCNTs. The high performance is attributed to the special porous structure of SZMC with large surface area created by the addition of MWCNTs and Zn, followed by chemical dezincification.
A facile method is developed to fabricate nanoporous, structured, Sn-based catalyst electrodes. Sn, Zn, and multiwalled carbon nanotubes (MWCNTs) are co-electrodeposited on a copper substrate, followed by chemical dezincification in NaOH aqueous solution to remove Zn. By controlling variables such as the contents of Zn and MWCNTs, a series of Sn-MWCNT/Cu (SZMC) electrodes are fabricated. Experimental results show that using such novel SZMC electrodes can achieve a HCOO- Faradaic efficiency of over 91% at -0.99 V versus RHE for 10 hours in CO2-saturated 0.5 M KHCO3 aqueous solution. The high performance is attributed to the addition of MWCNTs and Zn, followed by chemical dezincification to remove Zn and then create vacancies in the catalyst structure, which results in a special porous structure of SZMC with large surface area. Then ECSA is used for enhancing the catalytic activity and selectivity of HCOO- production, as well as promoting intermediate adsorption and mass transfer.
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