Journal
INORGANIC CHEMISTRY
Volume 60, Issue 2, Pages 561-565Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.0c03064
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Funding
- Key Research Program of Frontier Sciences, CAS [XDB20010100, QYZDB-SSW-SLH020]
- Youth Innovation Promotion Association of CAS
- National Natural Science Foundation of China [21871264, 21827813]
- Chinese Academy of Sciences [YJKYYQ20180006]
- Natural Science Foundation of Fujian Province [2018J01028]
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Novel open-framework Zn compound was synthesized with a 1D channel structure, showing promising performance in detecting aniline with unprecedented detection limits through luminescence emission.
Photochromic open-framework compounds are of potential application in detection/sensors. The issue of improving the detection limits has received much attention. We synthesized a new open-framework Zn compound, namely, compound 1 ([Zn(MQ)(IPA)Cl].5H(2)O) (MQ = N-methyl-4,4'-bipyridinium, IPA = m-phthalic acid), which showed a 1D channel structure by a cationic-pi interaction. It is noteworthy that this compound is an effective detector for aniline though luminescence emission, which exhibited unprecedented detection limits in photochromic open-framework compounds.
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