Journal
INORGANIC CHEMISTRY
Volume 59, Issue 24, Pages 17851-17855Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.0c02877
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Funding
- National Key Research and Development Program of China [2018YFA0208600]
- National Natural Science Foundation of China [21773242, 21935010]
- Youth Innovation Promotion of CAS [2016276]
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Presented here are two novel porous supramolecular boron imidazolate frameworks (BIF-106 and BIF-107), which are stabilized through relatively weak interactions between two-dimensional boron imidazolate layers. Moreover, BIF-107 exhibits efficient CO2 photoreduction to CO with a remarkable rate of 1186.0 mu mol.g(-1) .h(-1) under visible-light irradiation.
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