4.7 Article

Robust 4d-5f Bimetal-Organic Framework for Efficient Removal of Trace SO2 from SO2/CO2 and SO2/CO2/N2 Mixtures

Journal

INORGANIC CHEMISTRY
Volume 60, Issue 3, Pages 1310-1314

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.0c03526

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Funding

  1. National Science Foundations of China [21966002, 21871047, 21761001]
  2. Natural Science Foundation of Jiangxi Province of China [20181ACB20003]
  3. Training Program for Academic and Technical Leaders of Major Disciplines in Jiangxi Province [20194BCJ22010]

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This rare bimetal-organic framework exhibits high porosity and stability, enabling it to remove trace amounts of SO2 from a mixture even in humid conditions. This work not only introduces a novel adsorbent for SO2 removal, but also expands the functionality of actinium-based coordination compounds.
Herein, we report a highly rare robust 4d-5f bimetal-organic framework that shows high porosity and thermal/chemical stability and thus is capable of removing trace SO2 from a SO2/CO2/N-2 mixture even under humid conditions. This work not only shows a novel adsorbent for SO2 removal but also extends the function of actinium-based coordination compounds.

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