Journal
INORGANIC CHEMISTRY
Volume 59, Issue 23, Pages 17259-17267Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.0c02516
Keywords
-
Categories
Funding
- Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences Heavy Element Chemistry Program of the U.S. Department of Energy (DOE) at LBNL [DE-AC02-05CH11231]
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
- Goldwater Foundation
- National Science Foundation Graduate Research Fellowship Program [DGE 1106400]
- U.S. DOE Integrated University Program
- NIH [S10OD024998]
Ask authors/readers for more resources
A lithiated m-terphenyl ligand bearing fluorine atoms at the ortho positions of the flanking aryl rings was synthesized and characterized using single crystal X-ray diffraction, variable-temperature multinuclear NMR spectroscopy, and computational methods. Changes in (1)J(C,F) on coordination to lithium as a spectroscopic observable parametrizing the strength of the C-F center dot center dot center dot Li interaction are described, and a general, qualitative relationship between C-F bond lengths, Delta(1)J(C,F) values, and the extent of C-F bond activation as a result of Lewis acid coordination is proposed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
