Journal
FUEL
Volume 284, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2020.118937
Keywords
Crude oil; Liquid chromatography; PAH and PASH; Ring-number separation; Size exclusion mechanism; Molecular modeling
Categories
Ask authors/readers for more resources
The study aimed to elucidate the mechanisms involved in the limitations of achieving a clear-cut separation of alkylated aromatic compounds using normal-phase liquid chromatography. Evaluations were done with stationary phases to separate compounds based on the number of aromatic rings, revealing that the number of alkyl carbon atoms attached to the aromatic rings influenced the elution order. Molecular modeling calculations confirmed that the increase in alkyl carbon atoms increases molecular volume and impacts the separation of compounds. The counteractive role of the size exclusion mechanism was found to limit the application of normal-phase chromatography in this context.
There have been many attempts to achieve a clear-cut separation of alkylated aromatic compounds based on the number of aromatic rings employing normal-phase liquid chromatography. However, each method has its own limitations to address this issue. Therefore, we aimed to elucidate the involved mechanisms for this limitation. For this purpose, stationary phases viz. amino- and cyano-bonded silica gel were considered. The phases were evaluated with the distilled cuts of a crude oil based on resolution and selectivity, and the optimum phase was selected for the separation of a crude oil. It was observed that there was a significant overlap of compounds with the same ring-number in different peaks. The cause of overlap was linked to the number of alkyl carbon atoms attached to the aromatic rings. Aromatic compounds substituted with higher number of alkyl carbon atoms (total) elute earlier than those with lower number of alkyl carbon atoms. This trend was maintained for hydrocarbons, sulfur-containing compounds (S1), and di-sulfur containing compounds (S2). It was further corroborated using molecular modeling calculations that (i) the increase in the number of alkyl carbon atoms increases the molecular volume, and (ii) the volume of the molecules remains similar irrespective of the number and position of alkyl substituents provided that the total number of alkyl carbon atoms remains the same. Finally, it was revealed that the counteractive role of the size exclusion mechanism limits the application of normal-phase chromatography for a clear-cut separation of alkylated aromatic compounds according to the number of aromatic rings.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available