Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2021, Issue 4, Pages 648-652Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202001460
Keywords
C− N bond formation; Silver; Synthetic methods; Transition metals
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Funding
- Hangzhou Ledun Technology Co., Ltd
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A silver-catalyzed acyl nitrene transfer reaction involving dioxazolones, isocyanides, and water was successfully achieved in this study, leading to the synthesis of a series of N-acylureas in moderate to good yields. This provides a new research direction for the application of dioxazolones and isocyanides in synthetic chemistry.
Dioxazolones and isocyanides are useful synthetic building blocks, and have attracted significant attention from researchers. However, the silver-catalyzed nitrene transfer reaction of dioxazolones has not been investigated to date. Herein, a silver-catalyzed acyl nitrene transfer reaction involving dioxazolones, isocyanides, and water was realized in the presence of Ag2O to afford a series of N-acylureas in moderate to good yields.
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