Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume 2020, Issue 48, Pages 4502-4515Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.202000834
Keywords
Adsorption‐ driven heat pumps; Adsorption heat transformation; Metal‐ organic frameworks; Sorption materials; Water sorption
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Funding
- German Federal Ministry of Economics (BMWi) [0327851A/B]
- German Federal Ministry of Education and Research (BMFT) [03SF0492A/C]
- Projekt DEAL
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Cyclic physical adsorption and desorption processes on porous materials can be used for the conversion of heat in heat transformation processes, which is the working principle in adsorption heat pumps (AHPs). Environmentally benign water with its high enthalpy of evaporation is the working fluid of choice in AHPs. Metal-organic frameworks, MOFs can adsorb large amounts of water or methanol, up to their own weight. MOFs could be alternative materials to silica gels, zeolites, or aluminum phosphates for low-temperature heat transformations in AHPs.
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