Revealing the impact of water conservancy projects and urbanization on hydrological cycle based on the distribution of hydrogen and oxygen isotopes in water

In recent years, the development and utilization of water resources have imposed great impacts on hydrological characteristics and ecological environment. In this paper, methods based on stable isotopes were used to analyze the cumulative effect of water projects and urbanization on the hydrological cycle in Qingbaijiang River Basin. Isotope evidence shows that the hydrological processes affected by water regulation and urbanized runoff generation differentiate greatly from the natural state. The annual mean isotopic values follow an order of groundwater > rainwater > river water. Consistent isotopic composition and variation trend between the near-bank groundwater and river water were only observed from May to late June 2018 and from February to April 2019 in the upper zone, indicating the dominant recharge of river to the groundwater. However, the isotopic variations between the two waters in the middle and lower zones suggested that the hydraulic exchange was limited, demonstrating the significant changes in river water level caused by the reservoir impoundment. The isotopic enrichment rate along the flow path is highest in January (0.0265 parts per thousand/km), followed by October (0.0160 parts per thousand/km), indicating the significant evaporation, while slight spatial changes in July (0.0027 parts per thousand/km) reflected masked evaporation effect. This variability can be mainly attributed to the flow rate change and increase of water salinity in anthropic zones. Periodic regression analysis was employed to evaluate the difference in rainfall-runoff responses between hydrographic zones and estimate the mean residence time (MRT). Periodicity of isotopes in river water increased from upper to lower reaches with increasing R-2 values from 0.04 in SW1 to 0.46 in SW8. The MRT grew shorter along the flow path from 870 days in SW1 to 293 days in SW8, reflecting accelerated rainfall-runoff process due to the increasing impervious surface area and drainage system. These results identify the sensitivity of stable isotopes to the land use changes, runoff generation, and topography, and have implication for the potential water and environmental risks. Based on these understandings, suggestions for sustainable water-environment management in urban and rural areas were proposed.

Automated summary

The study used stable isotopes to analyze the impact of water projects and urbanization on the hydrological cycle, finding significant changes in natural hydrological processes due to urbanization and water projects. Isotopes were found to be closely related to river water level changes and showed distinct differences in rainfall-runoff responses in different areas. Stable isotopes are sensitive to land use changes and runoff generation, providing valuable insights for water resource and environmental risk assessment.