4.6 Review

Fluoridation-induced high-performance catalysts for the oxygen evolution reaction: A mini review

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 122, Issue -, Pages -

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2020.106901

Keywords

Fluoridation; Oxygen evolution reaction; Metal fluorides; Water splitting

Funding

  1. National Natural Science Foundation of China [21972124, 21603041]
  2. Priority Academic Program Development of Jiangsu Higher Education Institution

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Fluoridation has been found to play a significant role in the fabrication of oxygen evolution reaction catalysts, affecting structure transformation, surface engineering, electronic state tuning, and the formation and exposure of active phases. Various types of fluorine-containing catalysts have been developed, showing efficient active phase formation due to fluorine etching effect. This review discusses the advancements, challenges, and potential impacts of using fluoridation in catalyst fabrication for water-splitting reactions, aiming to provide guidance for the scientific community.
Fluoridation has recently been found to be significant in the fabrication of oxygen evolution reaction catalysts due to its influence on structure transformation, surface engineering, electronic state tuning, and the easy formation and exposure of active phases. Herein, we summarize recent advances in this area, including catalyst fabrication and performance in the water-splitting reaction. The catalysts are classified into transition metal fluorides, fluorine-doped and oxyfluoride compounds. All the fluorine-containing catalysts are reported to be efficient for active phase formation because of the increased strength of ionic bonds and the exposure of active sites caused by the fluorine etching effect. The problems and challenges of this approach are also discussed, and it is hoped that this review will be helpful to the scientific community.

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