4.4 Article

Fabrication of N-halamine polyurethane films with excellent antibacterial properties

Journal

E-POLYMERS
Volume 21, Issue 1, Pages 47-56

Publisher

WALTER DE GRUYTER GMBH
DOI: 10.1515/epoly-2021-0007

Keywords

polyurethane; N-halamine; chlorination; anti-bacterial; surface property

Funding

  1. Science and technology Project in Anhui Province [1704a0902018]
  2. Key Project of Natural Science in Universities of Anhui Province, China [KJ2016A792]

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The N-halamine precursor AHM was used as a chain extender in the preparation of N-halamine polyurethane films, improving their thermodynamic and mechanical properties. The chlorinated PU-AHM-Cl films showed significantly enhanced antibacterial properties against Escherichia coli and Staphylococcus aureus, offering potential applications in microbiological protection materials and related fields.
An N-halamine precursor, namely, 2-amino-5-(2-hydroxyethyl)-6-methylpyrimidin-4-one (AHM), was used as a chain extender in the preparation of a series of N-halamine polyurethane (PU) films, in order to also instill antibacterial properties. The mechanical properties, thermodynamic performance, and antimicrobial performance of the functionalized PU films were systematically studied. The results showed that the addition of AHM could improve the thermodynamic and mechanical properties of the developed PU films. Conducting tests in the presence of Escherichia coli and Staphylococcus aureus as the model microorganisms revealed that prior to chlorination the antibacterial properties of the chlorinated PU-AHM-Cl films improved significantly relative to the analogous films. The excellent antibacterial properties and the overall superior performance of the PU-AHM-Cl films allow their potential application in microbiological protection materials and related fields.

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