Journal
CRYSTAL GROWTH & DESIGN
Volume 21, Issue 2, Pages 1249-1258Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.0c01536
Keywords
-
Funding
- Nanodyn Systems Pty. Ltd.
Ask authors/readers for more resources
The precipitation kinetics of calcium oxalate were investigated using a novel acidic reaction rate control and pH-monitoring method. The research found that complex formation is remarkably favorable and is diffusion rate-limited. Nucleation reaction initiates via the molecular assembly of near-zwitterionically polarized complexes.
The precipitation kinetics of calcium oxalate was investigated using a novel acidic reaction rate control and pH-monitoring method and a sequence of acid-base, coordination, nucleation, and growth differential equations. The results indicate that the complex formation is remarkably favorable and is diffusion rate-limited. The nucleation reaction is shown to initiate via the molecular assembly of near-zwitterionically polarized complexes. From experimental results, growth and formation of the crystal phase leads to an enthalpically less stabilized state.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available