A comprehensive experimental and kinetic modeling study of 1-and 2-pentene

1- and 2-pentene are components in gasoline and are also used as representative alkene components in gasoline surrogate fuels. Most of the available ignition delay time data in the literature for these fuels are limited to low pressures, high temperatures and highly diluted conditions, which limits the kinetic model development and validation potential of these fuels. Therefore, ignition delay time measurements under engine-like conditions are needed to provide target data to understand their low-temperature fuel chemistry and extend their chemical kinetic validation to lower temperatures and higher pressures. In this study, both a high-pressure shock tube and a rapid compression machine have been employed to measure ignition delay times of 1- and 2-pentene over a wide temperature range (60 0-130 0 K) at equivalence ratios of 0.5, 1.0 and 2.0 in 'air', and at pressures of 15 and 30 atm. At high-temperatures (> 900 K), the experimental ignition delay times show that the fuel reactivities of 1and 2-pentene are very similar at all equivalence ratios and pressures. However, at low temperatures, 1-pentene shows negative temperature coefficient behavior and a higher fuel reactivity compared to 2-pentene. Moreover, carbon monoxide time-histories for both 1- and 2-pentene were measured in a high-pressure shock tube for a stoichiometric mixture at 10 atm and at high temperatures. Furthermore, species versus temperature profiles were measured in a jet-stirred reactor at = 1.0 and 1 atm over a temperature range of 70 0-110 0 K. All of these experimental data have been used to validate the current chemistry mechanism. Starting from a published pentane mechanism, modifications have been made to the 1and 2-pentene sub-mechanisms resulting in overall good predictions. Moreover, flux and sensitivity analyses were performed to highlight the important reactions involved in the oxidation process. (C) 2020 The Authors. Published by Elsevier Inc. on behalf of The Combustion Institute. This is an open access article under the CC BY license.

Automated summary

The study measured ignition delay times of 1- and 2-pentene using a high-pressure shock tube and a rapid compression machine. The results showed similar fuel reactivities of 1- and 2-pentene at high temperatures, but 1-pentene had higher fuel reactivity and exhibited negative temperature coefficient behavior at low temperatures. Further analysis and modifications were made to the chemical mechanism to improve predictions.