4.7 Article

Porous Ni/NiO nanohybrids for electrochemical catalytic glucose oxidation

Journal

CHINESE CHEMICAL LETTERS
Volume 32, Issue 6, Pages 2017-2020

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2020.11.066

Keywords

Porous; Ni/NiO; Nanohybrids; Electrocatalysis; Glucose

Funding

  1. National Natural Science Foundation of China (NSFC) [U1904215, 21671170]
  2. Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP)
  3. Program for Young Changjiang Scholars of the Ministry of Education, China [Q2018270]
  4. Priority Academic Program Development of Jiangsu Higher Education Institutions

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The study investigates a porous cuboid Ni/NiO composite nanomaterial obtained by calcining NiC2O4 center dot 2H(2)O under a N-2 environment, showing good electrocatalytic properties, high sensitivity, and improved electrochemical stability.
The remarkable development of nanotechnology and nanoscience has greatly promoted the vigorous development of the field of nanomaterials. This study explores a porous cuboid Ni/NiO composite nanomaterial obtained by calcining NiC2O4 center dot 2H(2)O under a N-2 environment. The composite affords direct electrochemical activity and good electrocatalytic properties. Compared to uncalcined precursor, the porous Ni/NiO obtained after calcination exhibited higher catalytic activity for glucose oxidation with higher sensitivity. Moreover, because of its regular cube structure the as-synthesized Ni/NiO exhibited improved electrochemical stability. Such porous Ni/NiO nanocubes represent promising glucose catalyst with high sensitivity and selectivity, improved stability and fast amperometric response. (C) 2021 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

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