Calibration of organic-diffusive gradients in thin films (o-DGT) passive samplers for perfluorinated alkyl acids in water

The application of the organic-diffusive gradients in thin films (o-DGT) passive sampling technique for the monitoring of per- and polyfluoroalkyl substances (PFAS) in the environment is still limited. Six common PFAS with different chain lengths were evaluated in water by o-DGT. Measured diffusion coefficients (D) in agarose and polyacrylamide diffusive gels ranged from 4.55-8.63 x 10(-6) cm(2) s(-1) and 3.85-7.00 x 10(-6) cm(2) s(-1) at 23 degrees C, respectively. Experimental sampling rates (Rs) for both agarose- and polyacrylamide-WAX sampler configurations were within 22% relative error of D-based Rs for four of the PFAS. Larger differences for perfluorobutanesulfonic acid (PFBS) and perfluoroundecanoic acid (PFUnDA) ranged from 36% to 56%. In general, in-situ Rs can be predicted using measured D-values for perfluorinated alkyl acids. The mass accumulation of six PFAS in two o-DGT configurations was linear over 21 days (R-2 >= 0.97). Diffusion and uptake of o-DGT depended on the gel type and specific PFAS. Field demonstrations of o-DGT with WAX and HLB binding gels and polyacrylamide diffusive gels (not prone to biodegradation) found 0.3-19.5 ng L-1 of PFAS in rivers near industrial areas around Guangzhou and Foshan, China, with no apparent differences between the two co-deployed samplers. This study demonstrates that the configurations of o-DGT tested provide a cost-effective monitoring tool for measuring perfluorinated alkyl acids in aquatic systems, in particular the four PFAS for which reasonable correlations were observed. (C) 2020 Elsevier Ltd. All rights reserved.

Automated summary

The study evaluated the use of o-DGT for monitoring PFAS in water, finding that in-situ sampling rates can be predicted using measured diffusion coefficients. The configurations of o-DGT tested provide a cost-effective monitoring tool for measuring perfluorinated alkyl acids in aquatic systems, particularly for four PFAS with reasonable correlations.