4.7 Article

Effect of high hydrostatic pressure-assisted pectinase modification on the Pb2+ adsorption capacity of pectin isolated from sweet potato residue

Journal

CHEMOSPHERE
Volume 262, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2020.128102

Keywords

Sweet potato pectin; High hydrostatic pressure; Pectinase; Pb2+ adsorption; Adsorption mechanism; Wastewater treatment

Funding

  1. China Agriculture Research System [CARS-10-B21]
  2. National Key R&D Program of China [2016YFE0133600]
  3. Collaborative Innovation Task of Chinese Academy of Agricultural Sciences [CAAS-XTCX2016005]
  4. Institute of Food Science and Technology, Chinese Academy of Agricultural Sciences

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The novel pectin derived from sweet potato residue modified by high hydrostatic pressure-assisted pectinase showed greater adsorption performance for Pb2+ than natural pectin, indicating potential as an environmentally friendly heavy metal adsorbent.
Novel pectin derived from sweet potato residue was modified by high hydrostatic pressure (HHP)-assisted pectinase and then used for Pb2+ removal from aqueous solutions. The removal characteristics and mechanisms were also investigated. Results showed that modified sweet potato pectin exhibited greater adsorption performances for Pb2+ than that of natural ones, and showed excellent eco-friendly properties and good potential for adsorption of some other heavy metals (such as Cu2+). The adsorption curves were much more conformed to Langmuir model, and the highest capacity for Pb2+ adsorption was 263.15 mg/g with 1.00% pectin at pH 7. Chemical adsorption process of pectin for Pb2+ absorption involved O-containing functional groups (O-H, COO-), cation exchange, and along with electrostatic interactions. Overall, the results in this study indicated that sweet potato pectin modified with HHP-assisted pectinase had the potential to become an environmentally friendly coagulant-flocculant agent for the heavy metal adsorption, especially for Pb2+. (C) 2020 Published by Elsevier Ltd.

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