Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 16, Issue 5, Pages 364-377Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.202001375
Keywords
asymmetric catalysis; homogeneous catalysis; gold; enantioselectivity; ligand design
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Funding
- Hong Kong Research Grants Council [PolyU 153000/19P]
- State Key Laboratory of Chemical Biology and Drug Discovery
- Hong Kong Polytechnic University (G-UACN)
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This review summarizes the rapid development of asymmetric gold catalysis in the past ten years, focusing on newly developed gold-catalyzed enantioselective organic transformations and recent progress in ligand design since 2016, organized according to different types of chiral ligands for asymmetric gold(I) and gold(III) catalysis.
Asymmetric gold catalysis has been rapidly developed in the past ten years. Breakthroughs have been made by rational design and meticulous selection of chiral ligands. This review summarizes newly developed gold-catalyzed enantioselective organic transformations and recent progress in ligand design (since 2016), organized according to different types of chiral ligands, including bisphosphine ligands, monophosphine ligands, phosphite-derived ligands, and N-heterocyclic carbene ligands for asymmetric gold(I) catalysis as well as heterocyclic carbene ligands and oxazoline ligands for asymmetric gold(III) catalysis.
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