Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 27, Issue 21, Pages 6500-6510Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202005198
Keywords
antimony; group 14; heterobimetallic complexes; magnesium; metallocenes
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Funding
- Deutsche Forschungsgemeinschaft (Emmy Noether Program) [SCHA1915/3-1]
- Fonds der Chemischen Industrie
- Projekt DEAL
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The transmetalation of magnesocenes can be used to synthesize metalocenes from different groups, showing novel coordination chemistry properties.
Several 1,1 '-diphosphanyl-substituted metallocenes of magnesium (magnesocenes) were synthesized, structurally characterized, and their reactivity and coordination chemistry were investigated. Transmetalation of these magnesocenes gives access to group 14 metallocenes (tetrelocenes), as well as to group 15 stibonocenes. These s- and p-block metallocenes represent a novel class of bis(phosphanyl) ligands, exhibiting Lewis-amphiphilic character. Their coordination chemistry towards different transition-metal and main-group fragments was investigated and different complexes are presented.
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