4.6 Article

Twisting versus Delocalization in CAAC- and NHC-Stabilized Boron-Based Biradicals: The Roles of Sterics and Electronics

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 27, Issue 16, Pages 5160-5170

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202004619

Keywords

ab initio calculations; boron; carbene ligands; density functional calculations; radicals

Funding

  1. DFG Graduate Research Training Group 2112 Molecular Biradicals: Structure, Properties and Reactivity
  2. Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES)
  3. Alexander von Humboldt (AvH) Foundation
  4. Projekt DEAL

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This issue features the research work of Bernd Engels, Holger Braunschweig, Volker Engel and their coworkers at University of Wurzburg on bridged boron compounds, highlighting the fascinating relationships between their composition, geometrical structures, and electronic structures.
Invited for the cover of this issue is Bernd Engels, Holger Braunschweig, Volker Engel and their coworkers at University of Wurzburg. The image depicts bridged boron compounds which possess fascinating relationships between their composition and their geometrical and electronic structures, the latter ranging from closed-shell to biradical triplet or singlet ground state. Read the full text of the article at 10.1002/chem.202004619.

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