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Molecular Functionalization of Carbon Nanotubes towards Near Infrared Photoluminescent Nanomaterials

Journal

CHEMISTRY LETTERS
Volume 50, Issue 3, Pages 397-404

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.200776

Keywords

Carbon nanotube; Exciton; Near infrared photoluminescence

Funding

  1. JSPS KAKENHI [JP17K17934, JP19H02557]
  2. Ministry of Education, Culture, Sports, Science and Technology, Japan

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Local chemical functionalization of single-walled carbon nanotubes has been developed to enhance the near infrared photoluminescence properties of the materials. The designed If-SWCNTs based on this approach exhibit wavelength-tunable and exciton trapping-induced bright emission, resulting in unique exciton properties.
Local chemical functionalization of single-walled carbon nanotubes (SWCNTs) has been developed as a means of defect doping to enhance the near infrared photoluminescence properties of the materials. Wavelength-tunable and exciton trapping-induced bright emission appears from locally functionalized SWCNTs (If-SWCNTs). Molecularly designed If-SWCNTs based on our approach produce new dynamic switching functionalities and greater shifts of the emission wavelength, which gives unique exciton properties to If-SWCNTs.

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