Journal
CHEMICAL RECORD
Volume 21, Issue 2, Pages 427-439Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.202000166
Keywords
asymmetric catalysis; salen complexes; epoxides opening; cooperativity; recycling
Categories
Funding
- Universite Paris Saclay
- CNRS
- Charm3At LabEx [ANR-11-LABEX-0039]
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Chiral cobalt-salen complexes have been essential for many asymmetric catalytic reactions due to their extraordinary reactivity and mode of action, as well as the processes towards optimizing their cooperativity for bimetallic activation and effective immobilization. The inspiring works dedicated to the discovery of their new reactivity continue to contribute to the field.
Since the discovery of their extraordinary reactivity in the hydrolytic kinetic resolution of terminal epoxides about twenty years ago, chiral cobalt-salen complexes have been shown to be essential for many other asymmetric catalytic reactions. This account summarizes the inspiring works dedicated to the discovery of their new reactivity and their mode of action, as well as the new processes towards the optimization of their cooperativity for bimetallic activation and the implementation of their effective immobilization, including also our contribution on these topics.
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