4.6 Review

Controlled-Potential-Based Electrochemical Sulfide Sensors: A Review

Journal

CHEMICAL RECORD
Volume 21, Issue 1, Pages 204-238

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.202000115

Keywords

electrochemical sulfide sensors; sensing strategies; direct electro-oxidation; electron-meditator-based oxidation; stripping

Funding

  1. King Abdulaziz City for Science and Technology (KACST) through the Science & Technology Unit at King Fahd University of Petroleum & Minerals (KFUPM), National Science, Technology and Innovation Plan [14-ENV332-04]

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This review article summarizes various strategies for detecting sulfide in different media and emphasizes essential parameters such as sensing strategies, working electrodes, detection media, pH, LOD, sensitivity, and linear detection range. Future research directions in this area are recommended.
Due to their potential applications in industry and potent toxicity to the environment, sulfides and their detection have attracted the attention of researchers. To date, a large number of controlled-potential techniques for electrochemical sulfide sensors have been developed, thanks to their simplicity, reasonable limit of detection (LOD), and good selectivity. Different researchers have applied different strategies for developing selective and sensitive sulfide sensors. However, there has been no systematic review on controlled-potential techniques for sulfide sensing. In light of this absence, the main aim of this review article is to summarize various strategies for detecting sulfide in different media. The efficiencies of the developed sulfide sensors for detecting sulfide in its various forms are determined, and the essential parameters, including sensing strategies, working electrodes, detection media, pH, LOD, sensitivity, and linear detection range, are emphasized in particular. Future research in this area is also recommended. It is expected that this review will act as a basis for further research on the fabrication of sulfide sensors for practical applications.

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