4.6 Article

Ag/TiO2 photocatalyst immobilized onto modified natural fibers for photodegradation of anthracene

Journal

CHEMICAL ENGINEERING SCIENCE
Volume 227, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2020.115939

Keywords

Photocatalysis; Ag/TiO2; Natural fibers; Anthracene; Photodegradat on; Wastewater

Funding

  1. CNPq
  2. PETROBRAS
  3. FAPESB

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This study reports the application of immobilized Ag/TiO2 onto coconut and sisal fibers to anthracene degradation via the UV-vis radiation. The fibers were previously treated with hot water and CTAB to clean their impurities surfaces. Immobilizations of Ag/TiO2 to the fibers were performed by anchorage of the catalysts via the post-synthesis method. The materials were characterized using AAS, TGA, XRD, UV-vis DRS, FTIR, STEM, EDS, and XPS analysis. FTIR and XPS results indicated the presence of hydroxyl groups and different silver species (Ago, Ag+, and Ag2+) on the catalyst surface. Immobilized Ag/TiO2 exhibited higher activity as compared to suspended Ag/TiO2 and TiO2. Ag/TiO2 immobilized on fibers treated with CTAB promoted the full anthracene photodegradation within 2 h at 40 degrees C. The results demonstrated that sisal and coconut fibers could be used as a support for Ag/TiO2. (C) 2020 Elsevier Ltd. All rights reserved.

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