4.7 Article

Long persistent luminescence properties of NaBaScSi2O7: Tb3+ and it's applications above room temperature

Journal

CHEMICAL ENGINEERING JOURNAL
Volume 401, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2020.126119

Keywords

Carriers; Crystal structure; Traps centers; Above room temperature

Funding

  1. National Nature Science Foundation of China (NSFC) [61965012, 11664022]
  2. Reserve talents project of Yunnan Province [2017HB011]
  3. Yunnan Ten Thousand Talents Plan Young & Elite Talents Project [YNWR-QNBJ2018-295, YNWR-QNBJ-2018-325]
  4. Excellent Youth Project of Yunnan Province Applied Basic Research Project [2019FI001]
  5. Foundation of Yunnan Province [2019HC016]

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Thermal energy induces long persistent luminescent (LPL) at room temperature, however, the performance is deteriorated for an accelerated release of carriers once these LPL phosphors were employed in an ambient environment with higher temperature such as in vivo imaging, or display in tropical environment. In this work, we report that NaBaScSi2O7 possessing stable crystal structure at high temperature, with the introduction of Tb3+ ions acting as emitting and traps centers, exhibits an obvious LPL properties above room temperature. The LPL time reaches more than 12 h at 353 K, thanks to the feasible trap depth ensuring the slowly release of the captured carriers. Outstanding chemical and physical stability guarantees the developed LPL phosphor could be applied for display and biological imaging above room temperature.

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