Journal
CHEMICAL ENGINEERING JOURNAL
Volume 403, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2020.126406
Keywords
Full-wood; Carbon quantum dots; Phase change materials; Photoluminescent; Photothermic
Categories
Funding
- National Natural Science Foundation of China [31770605, 31822008]
- Outstanding Youth Foundation of Heilongjiang [JC2018006]
- Fundamental Research Funds for the Central Universities [2572019BB04]
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Wood is commonly used to develop functional composites, but lignin is often discarded as waste. This study introduces a new approach to incorporate lignin derived carbon quantum dots back into delignified wood to create a full-wood material with photoluminescent, photothermic, and energy storage properties. This innovative technique shows promise for applications in energy-saving and optical devices.
Due to its unique structure and component, wood is widely used as matrix to develop functional composites. However, the lignin is removed from wood and thrown away as waste in most wood-based functional composites. In this work, a new strategy of taken from the wood, back into the wood to fabricate a full-wood photoluminescent and photothermic material is proposed. By facile delignification and solvothermal process, the delignified wood (DW) and carbon quantum dots (CQDs) derived from removal lignin are prepared. In addition, compared with other CQDs excited by UV light, the CQDs possess red (650 nm) and NIR (710 nm) emission light under visible light excitation (580 nm). Most importantly, the heat radiated from NIR emission could be stored by the introduced phase change materials (PCM) to adjust ambient temperature. The composite owns photoluminescent, photothermic and energy storage property (heat latent of 137.6 J/g), which is environmentally friendly, green and creative. The all-new technique for functional wood composite shows potential for application in energy-saving and optical devices.
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