Journal
CHEMCATCHEM
Volume 13, Issue 7, Pages 1753-1762Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202001925
Keywords
homoallylic phosphonates; β -ketophosphonates; palladium-catalyzed; (Z)-stereoselectivity; vinylethylene carbonates
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Funding
- National Natural Science Foundation of China [21871055]
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A first simple palladium catalyzed allylation of vinylethylene carbonates with beta-ketophosphonates has been developed, providing access to (Z)-tri- and tetrasubstituted homoallylic phosphonates with exclusive regioselectivity, chemoselectivity and (Z)-stereoselectivity. The reaction tolerates a wide substrate scope and works well on the gram scale.
A first simple palladium catalyzed allylation of vinylethylene carbonates with beta-ketophosphonates has been developed. This method provides access to (Z)-tri- and tetrasubstituted homoallylic phosphonates with exclusive regioselectivity, chemoselectivity and (Z)-stereoselectivity. The reaction tolerates a wide substrate scope of vinylethylene carbonates and beta-ketophosphonates with electron-donating and electron-withdrawing groups and works well on the gram scale.
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