Journal
CERAMICS INTERNATIONAL
Volume 47, Issue 7, Pages 10137-10146Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2020.12.162
Keywords
Silicide coating; Two-step pack cementation; Diffusion barrier; Oxidation; Molybdenum
Categories
Funding
- National Natural Science Foundation of China [51961019]
- Yunnan Province Science and Technology Major Project [202002AB080001]
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Using a two-step pack cementation method, double layers of MoSi2-MoB were applied on the surface of a Mo substrate to enhance its oxidation resistance at high temperatures. The formation of a dense and continuous SiO2 layer with low O-2 permeability contributed to the excellent high-temperature oxidation resistance of the double layers.
To improve the oxidation resistance of a Mo substrate at high temperatures, MoSi2-MoB double layers were prepared on the surface of the substrate using a two-step pack cementation method. The isothermal oxidation tests indicate that the weight loss of MoSi2-MoB double layers was only 6.3824 mg/cm(2) after oxidation at 1300 degrees C for 15 h, whereas the untreated Mo experienced serious weight loss and the weight loss was 606.775 mg/cm(2) after only 90 min. Following oxidation exposure, the oxidized coating became six complex layers due to correlation diffusion among Mo, Si and B. The double layers showed excellent high-temperature oxidation resistance due to the formation of a dense and continuous SiO2 layer with low O-2 permeability. Meanwhile, in situ fabrication of a novel Mo5SiB2 layer could prevent inward diffusion of Si.
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