4.8 Article

Electrospinning and in-situ hierarchical thermal treatment to tailor C-NiCo2O4 nanofibers for tunable microwave absorption

Journal

CARBON
Volume 171, Issue -, Pages 953-962

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2020.09.067

Keywords

C-NiCo2O4 nanofiber; Electrospinning; Thermal treatment; Microwave absorption

Funding

  1. National Natural Science Foundation of China [51977009, 11774027, 51372282, 51132002]

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A carbon-modified nickel cobalt oxide porous nanofiber material was successfully constructed using electrospinning and in-situ hierarchical thermal treatment engineering, with the ability to tune microwave absorption in different frequency bands. The material showed high electromagnetic absorption performance, making it promising for potential applications in multifunctional nano-micro electromagnetic devices.
The development of high-efficiency microwave absorbing materials in different frequency bands is expected to satisfy the requirement of real-time communication and national defense especially active camouflage in the information era. Herein, a carbon modified nickel cobalt oxide, C-NiCo2O4, porous nanofiber is successfully constructed by electrospinning and in-situ hierarchical thermal treatment engineering. The thermal treatment temperature enables tailoring of the C content of C-NiCo2O4 so as to modulate the conduction loss. More importantly, the absorption frequency can be tuned from K-u to X and even to C band due to that the proper tailoring affords varying synergy effect of dielectric and magnetic properties on impedance matching degree of each C-NiCo2O4 composite. Since low reflection loss suggests efficient energy conversion and heat generation, the high electromagnetic absorption makes the material extremely potential for application in multifunctional nano-micro electromagnetic devices. (C) 2020 Elsevier Ltd. All rights reserved.

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