4.7 Article

Environmentally friendly superabsorbent fibers based on electrospun cellulose nanofibers extracted from wheat straw

Journal

CARBOHYDRATE POLYMERS
Volume 251, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2020.117087

Keywords

Cellulose nanofibers; Electrospinning; Superabsorbent fibers; Wheat straw

Funding

  1. Iran's National science Foundation (INSF) [96012170]

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Superabsorbent fibers (SAFs) based on electrospun cellulose nanofibers (ECNFs) were prepared as a renewable alternative to petroleum-based materials, showing high swelling ratios and strength. The ESAFs formed high strength three-dimensional architecture networks and demonstrated low ionic sensitivity.
Superabsorbent polymers currently used in health and agricultural sectors are based on petroleum-based materials which led to serious concerns in the society. Here, superabsorbent fibers (SAFs) based on electrospun cellulose nanofibers (ECNFs) were prepared. Firstly, cellulose was removed from wheat straw, pre-treated with the TEMPO-mediated oxidation and subsequently dissolved into Trifluoroacetic acid for production of ECNFs through the electrospinning approach. The maximum swelling ratios of 225 g/g and 208 g/g in distilled water and 0.9 wt% NaCl solution were measured for ESAFs composed of oxidized ECNFs containing 15 % poly (sodium acrylate), respectively. The ESAFs were characterized using Fourier transform infrared spectroscopy and field emission scanning electron microscopy analysis. The FESEM showed that ESAFs formed high strength three-dimensional architecture networks. Also, the results showed that the ionic sensitivity of this ECNFs were low. The prepared ESAFs are attractive renewable alternatives for different applications, contributing to a reduction of plastic microspheres.

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