Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 16, Issue -, Pages 3032-3037Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.16.252
Keywords
fluorine; nucleophilic substitution; perfluoroalkylselenolation; selenium; trifluoromethylselenolation
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Funding
- French National Research Agency [ANR 18-CE07-0039-01]
- CNRS
- French Ministry of Research
- French Fluorine Network
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We report herein a practical method to generate CF3Se- (and RFSe-) anions from shelf-stable reagents under iodide activation. Metal-free nucleophilic trifluoromethylselenolations have been then performed with this in situ-generated anion. Perfluoroalkylselenolations have also been described.
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