Journal
DALTON TRANSACTIONS
Volume 45, Issue 1, Pages 237-245Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt03734d
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Funding
- Fondation Langlois and SATT Ouest-Valorisation
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New luminescent poly(methylmethacrylate) (PMMA) nanocomposites with high content of different hexanuclear octahedral cluster building blocks, namely [Mo6I8(C2F5COO6)](2-), [Re6Se8(CN)(6)](4-) and [W6Cl14](2-) have been prepared by free-radical polymerisation. To do so, cluster complexes bearing a polymerisable ammonium counter-cation have been synthesised. In this way, we demonstrate that ionic assembling is a powerful tool to functionalise easily any type of anionic cluster units to be introduced in a PMMA organic matrix. All samples remain homogeneous, stable during several months, and retain the luminescence properties of the cluster precursor.
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