4.6 Review

Recent advancements in organic synthesis catalyzed by graphene oxide metal composites as heterogeneous nanocatalysts

Journal

APPLIED ORGANOMETALLIC CHEMISTRY
Volume 35, Issue 4, Pages -

Publisher

WILEY
DOI: 10.1002/aoc.6162

Keywords

GO metal nanocomposites; Heck reaction; heterogeneous catalyst; organic synthesis; Suzuki reaction

Funding

  1. UGC-MANF [201819MANF-2018-19-RAJ-91971]
  2. CSIR [09/172(0088)/2018-EMR-I]

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In recent decades, heterogeneous catalysis, especially metal-based graphene oxide (GO) catalysts, has emerged as a promising approach for sustainable synthesis due to their unique properties. This article discusses the catalytic efficiency of various metal-supported GO catalysts in different organic transformations, such as oxidation, reduction, and multicomponent reactions. It aims to summarize the uses of metal-supported GO in the preparation of diverse synthetic molecules and the recent advancements in GO metal composites as catalysts.
In the last decades, heterogeneous catalysis has emerged as a promising approach for sustainable synthesis. Among this, metal-based graphene oxide (GO) as catalysts is widely used due to their unique properties such as physical and thermal stability of the catalysts in successive reaction runs and reusability. Metal-supported GOs are quite prevalent and probably suitable acidic catalysts for both research laboratories and industrial processes. Herein, we have described the catalytic efficiency of various metal-supported GO catalysts in different organic transformations like oxidation, reduction, multicomponent reactions, alkylation, condensation, dehydration, dehydrogenation, and Suzuki, Heck, and Sonogashira reactions. This article has been divided into three subsections: (i) GO-supported metal as a catalyst, (ii) GO-supported bimetal as a catalyst, and (iii) GO-supported metal oxide as a catalyst for the easier understanding of the vast community of researchers. The foremost aim of this article is to summarize the uses of metal-supported GO in the preparation of diverse synthetic molecules. The recent advancements in GO metal composites as catalysts with their applications have been deliberated.

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