Journal
DALTON TRANSACTIONS
Volume 45, Issue 27, Pages 11101-11108Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt01149g
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Funding
- CNRS
- ANR agency (program blanc Ironhyc) [12-BS07-0011-01]
- ANR agency (program JCJC Ferracycles) [ANR-15-CE07-0001]
- University of Rennes 1
- Fondation Rennes 1
- Agence Nationale de la Recherche (ANR) [ANR-15-CE07-0001] Funding Source: Agence Nationale de la Recherche (ANR)
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A new and efficient method based on the simple metalating reagent Fe(CO)(5) has been developed for the straightforward synthesis of well defined cyclometalled PCP iron carbonyl pincer complexes. The reaction proceeds cleanly under mild conditions at 30 degrees C and UV irradiation. Four hydride pincer complexes are synthesized and fully characterized as well as an intermediate dinuclear species. The new iron complexes are active and selective catalytic precursors for the dehydrogenative borylation of styrene with HBpin.
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