4.7 Article

3D Nitrogen-rich metal-organic frameworks: opportunities for safer energetics

Journal

DALTON TRANSACTIONS
Volume 45, Issue 6, Pages 2363-2368

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt04456a

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Funding

  1. Office of Naval Research [NOOO14-12-1-0536]
  2. Defense Threat Reduction Agency [HDTRA 1-11-1-0034]
  3. CFD Research Corporation

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Metal-organic frameworks, particularly those coordinated with nitrogen-rich ligands, are extremely versatile materials. Here the structural factors and performances of 1D and 2D energetic MOFs are compared briefly with those of 3D species. Advantages of hydrothermal in situ synthesis, properties of azole-based ligands, and choices of environmentally friendly metal ions for 3D energetic MOFs are also explored.

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