Journal
DALTON TRANSACTIONS
Volume 45, Issue 6, Pages 2476-2484Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt04729c
Keywords
-
Categories
Ask authors/readers for more resources
An N-pivot diglycolamide extractant (DGA-TREN) was synthesized for the first time and its complexation behaviour was studied towards trivalent lanthanide/actinide ions. The solvent extraction studies suggested a unique selectivity reversal in the extraction of trivalent actinides versus trivalent lanthanides which was observed performing extraction studies in an ionic liquid vis-a-vis a molecular diluent for a tripodal TREN-based diglycolamide ligand (DGA-TREN) vs. a tripodal diglycolamide ligand (T-DGA) which may have great significance in radioactive waste remediation. The nature of the bonding to Eu3+ ion was investigated by EXAFS as well as by DFT calculations.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available