Journal
DALTON TRANSACTIONS
Volume 45, Issue 34, Pages 13317-13323Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt01552b
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Funding
- National Natural Science Foundation of China Major Project [91122030]
- National Natural Science Foundation of China [51102229, 51402288, 21401184]
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A novel dichromic luminescence probe SrO:Eu3+, Bi3+ for temperature sensing is achieved. The detailed luminescence properties, e.g., the excitation emission spectra, energy transfer efficiency, luminescence decay lifetimes and temperature dependent luminescence are comprehensively studied. The two dominant emissions D-5(0) -> F-7(2) transition of Eu3+ and the P-3(1) -> S-1(0) transition of Bi3+ display adjustable spectrum area. The interaction effect between Eu3+ and Bi3+ are proposed. The dichromic emissions are specifically responding to temperature with high sensitivity at ultra-wide range from 30 to 400 degrees C. Spatial and temporal temperature images on an aircraft surface have been successfully realized under excitation of commercial 365 nm light emitting diode (LED) by painting the SrO: Bi3+, Eu3+ phosphor on a plane model. Finally, the thermal quenching mechanism revealed by Arrhenius theory is employed to interpret the temperature sensitive luminescence behaviour.
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